Reusable ionic liquid-catalyzed oxidative coupling of azoles and benzylic compounds via sp(3) C-N bond formation under metal-free conditions.

نویسندگان

  • Wenbo Liu
  • Chenjiang Liu
  • Yonghong Zhang
  • Yadong Sun
  • Ablimit Abdukadera
  • Bin Wang
  • He Li
  • Xuecheng Ma
  • Zengpeng Zhang
چکیده

The heterocyclic ionic liquid-catalyzed direct oxidative amination of benzylic sp(3) C-H bonds via intermolecular sp(3) C-N bond formation for the synthesis of N-alkylated azoles under metal-free conditions is reported for the first time. The catalyst 1-butylpyridinium iodide can be recycled and reused with similar efficacies for at least eight cycles.

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عنوان ژورنال:
  • Organic & biomolecular chemistry

دوره 13 26  شماره 

صفحات  -

تاریخ انتشار 2015